Authors: Jiahui Hou & Zifei Meng
Advisor: Professor Yan Wang
Category: Graduate
Abstract: The demand for rechargeable lithium-ion batteries (LIBs) has increased exponentially since they were first commercialized by Sony in 1991. [1] Due to the high energy density and excellent cycle stability, LIBs have been widespread utilized in electric vehicles and other applications. However, the lifespan of LIBs is limited. Thus, tons of spent LIBs are generated during the recent decades. More importantly, the price of raw materials, including lithium and cobalt salts, for producing LIBs grows significantly. [2, 3] Therefore, recycling these End-of-Life LIBs becomes a non-negligible part in the whole manufacturing process and hydrometallurgical process is the most common recycling method. Here, our group has demonstrated a closed loop recycling process, combining inorganic acid etching and coprecipitation reaction, to produce regenerated Ni-rich cathode materials. The regenerated LiNi0.83Mn0.06Co0.11O2 shows excellent performance: the first cycle discharge capacity is 214.1mAh/g at 0.05C in the voltage range of 2.8 – 4.3V and the initial columbic efficiency is 90.9%. The performance of our regenerated cathode materials is comparable to commercial cathode materials. In order to further optimize the properties of the regenerated LiNi0.83Mn0.06Co0.11O2, different elements, like Al, with various doping or coating methods will be utilized.
UN SDGs:
SDG 9 – Industry, Innovation, and Infrastructure
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